Which of the following is the weakest acid?

What is $Z$ in the following reactions?

In the following sets of reactants,which two sets best exhibit the amphoteric character of $Al_2O_3 \cdot xH_2O$?
Set $1$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $OH^{-}_{(aq)}$
Set $2$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $H_2O_{(l)}$
Set $3$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $H^{+}_{(aq)}$
Set $4$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $NH_{3(aq)}$

Aluminium is not used:

Hybridisation of boron in diborane is

Boron does not form $B^{3+}$ cation easily. It is due to