Which of the following is the first fungicide?

Which of the following is an incorrect pair?

Match the columns:

Column-$I$	Column-$II$
$(a)$ Carrot	$(1)$ Vitamin $C$
$(b)$ Bitter gourd	$(2)$ Protein
$(c)$ Spinach	$(3)$ Vitamin $A$
$(d)$ Peas	$(4)$ Vitamin $B_{12}$
	$(5)$ Iron

Find the mismatched pair:

Statement $A$: High-quality disease-free plants and animals are produced.
Reason $R$: Through animal husbandry and tissue culture,food production can be increased to meet the needs of the growing human population.
Which option is correct for Statement $A$ and Reason $R$?

Green revolution is related to the increase in