Which of the following statements is not correct?

  • A
    $Mn_2O_7$ gives $HMnO_4$ on reaction with water.
  • B
    On heating,$AgNO_3$ gives $Ag$,$NO_2$,and $O_2$.
  • C
    $V_2O_5$ is amphoteric and dissolves in alkalies to give $VO_4^{3-}$ ions.
  • D
    All of the above are incorrect.

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The correct order of oxidizing power of the given ions is

Fill in the blanks:
$(a)$ The only $Mn$ halide compound that shows an oxidation state of $+7$ is ........
$(b)$ The $E^{\ominus}_{M^{II}/M}$ value is maximum negative for ........ in the $3d$ series.
$(c)$ Between $Cr^{2+}$ and $Fe^{2+}$,the stronger reducing agent is ........

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Iron is rendered passive by treatment with

$\underset{\text{coloured}}{P(\text{soln.})}$ $\xrightarrow{\text{Air}} \underset{\text{coloured}}{Q(\text{soln.})}$ $\xrightarrow{KOH} R \downarrow$
$(R = \text{ppt. Insoluble in both excess } NaOH \text{ and excess } NH_3 \text{ solution})$
Then $P$ contains

How would you account for the following:
$(i)$ Of the $d^{4}$ species,$Cr^{2+}$ is strongly reducing while $Mn^{3+}$ is strongly oxidising.
$(ii)$ $Co^{2+}$ is stable in aqueous solution but in the presence of complexing reagents it is easily oxidised.
$(iii)$ The $d^{1}$ configuration is very unstable in ions.

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