Which of the following is incorrectly matched?

Match the following:

List-$I$	List-$II$
$A$. $ABCABC...$ layers	$I$. $F$-centres
$B$. Thermodynamics defects	$II$. $X$-ray diffraction
$C$. $Farbenzenter$	$III$. Vacancy defects
$D$. $Debye-Scherrer$ method	$IV$. Semiconductors
	$V$. Silver

Which of the following statement(s) is (are) correct?

Atoms of metals $x$,$y$,and $z$ form face-centred cubic $(fcc)$ unit cell of edge length $L_x$,body-centred cubic $(bcc)$ unit cell of edge length $L_y$,and simple cubic unit cell of edge length $L_z$,respectively. If $r_z = \frac{\sqrt{3}}{2} r_y$; $r_y = \frac{8}{\sqrt{3}} r_x$; $M_z = \frac{3}{2} M_y$ and $M_z = 3 M_x$,then the correct statement$(s)$ is (are) [Given: $M_x$,$M_y$,and $M_z$ are molar masses of metals $x$,$y$,and $z$,respectively. $r_x$,$r_y$,and $r_z$ are atomic radii of metals $x$,$y$,and $z$,respectively.]
$(A)$ Packing efficiency of unit cell of $x >$ Packing efficiency of unit cell of $y >$ Packing efficiency of unit cell of $z$
$(B)$ $L_y > L_z$
$(C)$ $L_x > L_y$
$(D)$ Density of $x >$ Density of $y$

Select the correct statement.

Silver (atomic weight $= 108 \ g \ mol^{-1}$) has a density of $10.5 \ g \ cm^{-3}$. The number of silver atoms on a surface of area $10^{-12} \ m^2$ can be expressed in scientific notation as $y \times 10^x$. The value of $x$ is