Which of the following ions does not liberate hydrogen gas on reaction with dilute acids?

  • A
    $Ti^{2+}$
  • B
    $V^{2+}$
  • C
    $Cr^{2+}$
  • D
    $Mn^{2+}$

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The ${E^0}_{M^{3+}/M^{2+}}$ values for $Cr, Mn, Fe$ and $Co$ are $-0.41, +1.57, +0.77$ and $+1.97 \ V$ respectively. For which one of these metals is the change in oxidation state from $+2$ to $+3$ the easiest?

The set of correct statements is:
$(i)$ Manganese exhibits $+7$ oxidation state in its oxide.
$(ii)$ Ruthenium and Osmium exhibit $+8$ oxidation state in their oxides.
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$(iv)$ $Cr$ shows oxidizing nature in $+6$ oxidation state.

Passivity of iron is due to the formation of

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