Which of the following has the lowest barrier to rotation about the indicated bond?

  • A
    Cyclopentane (bond between $C_1$ and $C_2$)
  • B
    Buta$-1,3-$diene (bond between $C_2$ and $C_3$)
  • C
    n-Butane (bond between $C_2$ and $C_3$)
  • D
    $2,3-$Dimethylbutane (bond between $C_2$ and $C_3$)

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Wurtz reaction of methyl iodide yields an organic compound $X$. Which one of the following reactions also yields $X$?

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Among the following free radical bromination reactions,select those in which a $2^o$ halide is the major product. The reactions are as follows:
$(P)$ Cyclohexane + $Br_2/hv$
$(Q)$ Methylcyclobutane + $Br_2/hv$
$(R)$ Ethylbenzene + $Br_2/hv$
$(S)$ $3-$Methylhexane + $Br_2/hv$
$(T)$ Decalin + $Br_2/hv$
$(U)$ Butane + $Br_2/hv$

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