Which of the following gas mixtures is not applicable for Dalton's law of partial pressure?

$60 \ cm^3$ of $SO_2$ gas diffused through a porous membrane in '$x$' min. Under similar conditions $360 \ cm^3$ of another gas (molar mass $4 \ g \ mol^{-1}$) diffused in '$y$' min. The ratio of $x$ and $y$ is

Equal masses of three non-reacting different ideal gases $X, Y$ and $Z$ are mixed in a sealed rigid container. If the temperature of the system remains constant at $400 \ K$,which of the following statements about gas $X$ can never be correct?

Assertion : We feel cold on touching the ice.
Reason : Ice is a solid form of water.

At $STP$,$0.50 \ mol$ $H_2$ gas and $1.0 \ mol$ $He$ gas:

$A$ mixture of equal masses of $SO_2$,$CH_4$,and $O_2$ is taken in an empty container at $298 \, K$. If the total pressure is $2.1 \, atm$,the partial pressure of $CH_4$ in the mixture will be .......... $atm$.