Which of the following expressions represents the first law of thermodynamics?

At $1 \ bar$ pressure,a gas has a volume of $0.6 \ L$. If this gas gains $122 \ J$ of heat at $1 \ bar$ pressure,its volume becomes $2 \ L$. Calculate its internal energy change. [Given: $1 \ L \cdot bar = 101.32 \ J$]

If $\Delta E$ is the heat of reaction for $C_2H_5OH_{(l)} + 3O_{2(g)} \longrightarrow 2CO_{2(g)} + 3H_2O_{(l)}$ at constant volume,the $\Delta H$ (heat of reaction at constant pressure) at constant temperature is

Two moles of an ideal gas are allowed to expand from a volume of $10 \ dm^3$ to $2 \ m^3$ at $300 \ K$ against a pressure of $101.325 \ kPa$. Calculate the work done. (in $kJ$)

The gas absorbs $100 \ J$ and is simultaneously compressed by a constant external pressure of $1.50 \ atm$ from $8 \ L$ to $2 \ L$ volume. Hence $\Delta U$ will be ..... $J$.

For the reaction $N_{2(g)} + 3H_{2(g)} \rightarrow 2NH_{3(g)}$ at $298 \ K$,the enthalpy change $(\Delta H)$ is $-92.38 \ kJ$. What will be the internal energy change $(\Delta U)$ at $298 \ K$ in $kJ$?