Which of the following equations has $\Delta_{f} H^{\circ}$ and $\Delta H^{\circ}$ the same?

  • A
    $H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_{2}O_{(l)}$
  • B
    $N_{2(g)} + \frac{3}{2} O_{2(g)} \longrightarrow N_{2}O_{3(g)}$
  • C
    $CH_{4(g)} + 2 Cl_{2(g)} \longrightarrow CH_{2}Cl_{2(g)} + 2 HCl_{(g)}$
  • D
    $CO_{(g)} + \frac{1}{2} O_{2(g)} \longrightarrow CO_{2(g)}$

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What do you understand by exothermic reaction and endothermic reaction? Give one example of each type.

For the reaction $2H_2O_2(\ell) \to 2H_2O(\ell) + O_2(g)$,what is the enthalpy change? Given that the heats of formation of $H_2O_2(\ell)$ and $H_2O(\ell)$ are $-188 \, kJ/mol$ and $-286 \, kJ/mol$ respectively.

Calculate the enthalpy for the following reaction using the given bond energies $(kJ/mol)$:
$(C-H = 414; O-H = 463; H-Cl = 431; C-Cl = 326; C-O = 335)$
$CH_3OH_{(g)} + HCl_{(g)} \rightarrow CH_3Cl_{(g)} + H_2O_{(g)}$

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If the bond formation energy of the $H-H$ bond is $-433 \ kJ \ mol^{-1}$,find the bond dissociation energy for $0.5 \ mol$ of $H_{2(g)}$. (in $kJ$)

Based on the following thermochemical reactions:
$H_2O_{(g)} + C_{(s)} \rightarrow CO_{(g)} + H_{2(g)} ; \Delta H = 131 \ kJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow CO_{2(g)} ; \Delta H = -282 \ kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O_{(g)} ; \Delta H = -242 \ kJ$
$C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)} ; \Delta H = x \ kJ$
The value of $x$ will be:

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