Which of the following do not give aliphatic | vedclass

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(B) $CH_3-CH=N-OH$ (acetaldoxime) undergoes Beckmann rearrangement to form an amide or dehydration to form a nitrile; it does not produce an aliphatic

Vedclass · Accepted Answer

$CH_3-CH=N-OH \xrightarrow[\Delta]{H^{+}}$

Vedclass · Answer

(B) $CH_3-CH=N-OH$ (acetaldoxime) undergoes Beckmann rearrangement to form an amide or dehydration to form a nitrile; it does not produce an aliphatic primary amine.$(a)$ Schmidt reaction: $CH_3-COOH + N_3H \xrightarrow{H_2SO_4} CH_3-NH_2 + CO_2 + N_2$$(c)$ Hofmann bromamide reaction: $CH_3-CONH_2 + Br_2 + 4OH^{-} \rightarrow CH_3-NH_2 + CO_3^{2-} + 2Br^{-} + 2H_2O$$(d)$ Hydrolysis of isocyanide: $CH_3-NC + 2H_2O \xrightarrow{H^{+}} CH_3-NH_2 + HCOOH$

Which of the following do not give aliphatic primary amine as a product?

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