Which of the following curves is correct?

For the reaction $CH_{4(g)} + 2O_{2(g)} \rightleftharpoons CO_{2(g)} + 2H_{2}O_{(g)}$ with $\Delta H = -170.8 \ kJ \ mol^{-1}$,which of the following statements is incorrect?

The equilibrium constants of the following are
$N_2 + 3H_2 \rightleftharpoons 2NH_3 \,; \quad K_1$
$N_2 + O_2 \rightleftharpoons 2NO \,; \quad K_2$
$H_2 + \frac{1}{2} O_2 \rightleftharpoons H_2O \,; \quad K_3$
The equilibrium constant $(K)$ of the reaction:
$2NH_3 + \frac{5}{2} O_2 \rightleftharpoons 2NO + 3H_2O$ is:

For the equilibrium:
$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$; $K_{p} = 1.64 \ atm$ at $1000 \ K$.
$50 \ g$ of $CaCO_{3}$ in a $10 \ L$ closed vessel is heated to $1000 \ K$. The percentage of $CaCO_{3}$ that remains unreacted at equilibrium is:
(Given $R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1}$)

$K_{c}$ for the following reaction is $99.0$: $A_{2(g)} \rightleftharpoons B_{2(g)}$. In a $1 \ L$ flask,$2 \ moles$ of $A_{2}$ were heated to $T(K)$ and equilibrium was reached. The concentrations at equilibrium of $A_{2}$ and $B_{2}$ are $C_{1}(A_{2})$ and $C_{2}(B_{2})$ respectively. Now,$1 \ mole$ of $A_{2}$ was added to the flask and heated to $T(K)$ to establish equilibrium again. The concentrations of $A_{2}$ and $B_{2}$ are $C_{3}(A_{2})$ and $C_{4}(B_{2})$ respectively. What is the value of $C_{3}(A_{2})$ in $mol \ L^{-1}$?

The following reaction is performed at $298 \, K$.
$2 NO_{(g)} + O_{2(g)} \rightleftharpoons 2 NO_{2(g)}$
The standard free energy of formation of $NO_{(g)}$ is $86.6 \, kJ/mol$ at $298 \, K$. What is the standard free energy of formation of $NO_{2(g)}$ at $298 \, K$? $(K_p = 1.6 \times 10^{12})$