Which of the following compounds can form alcohol with $NaNO_2/HCl$?

  • A
    $(CH_3)_3C-NH_2$
  • B
    $(CH_3)_2CH-NH_2$
  • C
    $CH_3-CH_2-NH_2$
  • D
    All of these

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Given below are two statements:
Statement $I$: $o$-Phenylenediamine can be synthesized from $o$-xylene using simpler reagents in the order: $i)$ Acidic $KMnO_4$,$ii)$ Ammonia,$iii)$ Bromine and alkali.
Statement $II$: Aniline can be converted into benzene using reagents in the order: $(i)$ Bromine-$H_2O$,$(ii)$ $NaNO_2 / HCl$ $(0-5^{\circ} C)$,$(iii)$ aq. $H_3PO_2$.
In the light of the above statements,choose the correct answer from the options given below.

An aromatic compound $A$ on treatment with aqueous ammonia and heating forms compound $B$,which on heating with $Br_2$ and $KOH$ forms a compound $C$ of molecular formula $C_6H_7N$. Write the structures and $IUPAC$ names of compounds $A, B$,and $C$.

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Arrange the following:
$(i)$ In decreasing order of the $pK_{b}$ values:
$C_{2}H_{5}NH_{2}, C_{6}H_{5}NHCH_{3}, (C_{2}H_{5})_{2}NH$ and $C_{6}H_{5}NH_{2}$
$(ii)$ In increasing order of basic strength:
$C_{6}H_{5}NH_{2}, C_{6}H_{5}N(CH_{3})_{2}, (C_{2}H_{5})_{2}NH$ and $CH_{3}NH_{2}$
$(iii)$ In increasing order of basic strength:
$(a)$ Aniline,$p-$nitroaniline and $p-$toluidine
$(b)$ $C_{6}H_{5}NH_{2}, C_{6}H_{5}NHCH_{3}, C_{6}H_{5}CH_{2}NH_{2}$
$(iv)$ In decreasing order of basic strength in gas phase:
$C_{2}H_{5}NH_{2}, (C_{2}H_{5})_{2}NH, (C_{2}H_{5})_{3}N$ and $NH_{3}$
$(v)$ In increasing order of boiling point:
$C_{2}H_{5}OH, (CH_{3})_{2}NH, C_{2}H_{5}NH_{2}$
$(vi)$ In increasing order of solubility in water:
$C_{6}H_{5}NH_{2}, (C_{2}H_{5})_{2}NH, C_{2}H_{5}NH_{2}$

Consider the following sequence of reactions:
Chlorobenzene $\xrightarrow[ii) CO_2, H_3O^{+}]{i) Mg, \text{dry ether}} \text{Benzoic acid}$ $\xrightarrow{NH_3, \Delta} \text{Benzamide (A)}$ $\xrightarrow{Br_2, NaOH} \text{Aniline (B)}$
$11.25 \ mg$ of chlorobenzene will produce $.......... \times 10^{-1} \ mg$ of product $B$.
(Consider the reactions result in complete conversion.)
[Given molar mass of $C, H, O, N$ and $Cl$ as $12, 1, 16, 14$ and $35.5 \ g \ mol^{-1}$ respectively]

What is the major product of the following reaction? $C_2H_5-CONH_2$ $\xrightarrow{Br_2 / KOH} A$ $\xrightarrow{CHCl_3 / KOH} \text{Major Product}$

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