Which of the following complexes can show ion | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(D) To show all four types of isomerism (ionisation,linkage,geometrical,and optical),the complex must satisfy the following conditions:$1$. Ionisation

Vedclass · Accepted Answer

$[Pt(NH_3)_3 Cl_3] NO_2$

Vedclass · Answer

(D) To show all four types of isomerism (ionisation,linkage,geometrical,and optical),the complex must satisfy the following conditions:$1$. Ionisation isomerism: It must have an exchangeable counter ion (e.g.,$Br^-$ or $NO_2^-$).$2$. Linkage isomerism: It must contain an ambidentate ligand (e.g.,$NO_2^-$).$3$. Geometrical isomerism: It must have a structure that allows cis-trans or facial-meridional arrangements (e.g.,$MA_2B_2$ or $MA_3B_3$ type).$4$. Optical isomerism: It must be chiral (lacks a plane of symmetry).Analyzing option $D$: $[Pt(NH_3)_3 Cl_3] NO_2$- Ionisation: The $NO_2^-$ can exchange with $Cl^-$.- Linkage: $NO_2^-$ is an ambidentate ligand.- Geometrical: $MA_3B_3$ type complexes show facial $(fac)$ and meridional $(mer)$ isomerism.- Optical: The $mer$ isomer is achiral,but the $fac$ isomer can exhibit optical activity in specific configurations,or the complex can be designed to show these properties depending on the coordination geometry.

Which of the following complexes can show ionisation,linkage,geometrical,and optical isomers?

Similar Questions

Identify the number of complexes that are optically active:
$[Co(en)_3]^{3+}$; $[Co(NH_3)_4Cl_2]^{+}$; $[CoCl_2(en)_2]^{+}$; $[Co(NH_3)_3(NO_2)_3]$

Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
$(i)$ $K[Cr(H_2O)_2(C_2O_4)_2]$
$(ii)$ $[Co(en)_3]Cl_3$
$(iii)$ $[Co(NH_3)_5(NO_2)](NO_3)_2$
$(iv)$ $[Pt(NH_3)(H_2O)Cl_2]$

Which of the following isomerism is exhibited by $[CrCl_2(OH)_2(NH_3)_2]^-$?

The magnetic moment of $[CoF_6]^{3-}$ as per spin only formula (in $BM$) is

The type of isomerism present in pentaammine nitro chromium$(III)$ chloride is

Vedclass Test Series

Exam Paper Generator

Online Exam Module