Which of the following can not undergo hydrol | vedclass

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(D) Hydrolysis of a compound requires the presence of vacant $d$-orbitals on the central atom to accept the lone pair of electrons from the oxygen ato

Vedclass · Accepted Answer

Both $NF_3$ and $CCl_4$

Vedclass · Answer

(D) Hydrolysis of a compound requires the presence of vacant $d$-orbitals on the central atom to accept the lone pair of electrons from the oxygen atom of water,or the presence of a highly polar bond.$NF_3$ does not undergo hydrolysis because nitrogen lacks vacant $d$-orbitals and the $N-F$ bond is very strong,making it kinetically inert.$CCl_4$ does not undergo hydrolysis because carbon lacks vacant $d$-orbitals to accommodate the incoming water molecule,and the $C-Cl$ bond is sterically hindered.$NCl_3$ undergoes hydrolysis to form $NH_3$ and $HOCl$ because the $N-Cl$ bond is polar and the chlorine atom can stabilize the transition state.Therefore,both $NF_3$ and $CCl_4$ do not undergo hydrolysis.

Which of the following can not undergo hydrolysis?

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