Which of the following aqueous solutions has the highest boiling point,under identical conditions having a concentration of $0.03 \ m$?

$A$ solution of $CaCl_2$ is prepared by dissolving $0.0112 \ g$ of $CaCl_2$ in $1 \ kg$ of distilled water. If the molal freezing point depression constant $(K_f)$ of water is $2 \ K \ kg \ mol^{-1}$,what is the depression in the freezing point of the solution? (Assume $100\%$ ionization of $CaCl_2$)

$0.6 \, mL$ of acetic acid $(CH_{3}COOH)$,having density $1.06 \, g \, mL^{-1}$,is dissolved in $1 \, L$ of water. The depression in freezing point observed for this strength of acid was $0.0205^{\circ} \, C$. Calculate the van't Hoff factor and the dissociation constant of acid.

Which of the following aqueous solutions should have the highest boiling point?

At a constant temperature,the vapor pressures of aqueous solutions of $Na_2SO_4$,urea,$AlCl_3$,and $1.2 \, m \, KCl$ are approximately equal. The molalities of the aqueous solutions of $Na_2SO_4$,urea,and $AlCl_3$ are,respectively: (Assume $100 \%$ dissociation of the solute)

Find the expected value of $\Delta T_{b}$ for $1 \ m \ AlCl_3$ solution in water if a solution of a nonelectrolyte of the same concentration has a $\Delta T_{b}$ value of '$x$' $K$.