Which of the following does not react with HN | vedclass

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(D) The reaction with $HNO_2$ (nitrous acid) depends on the functional group present:$1$. $CH_3CH(CH_3)NO_2$ is a secondary nitroalkane. It reacts wit

Vedclass · Accepted Answer

$(CH_3)_3CNO_2$

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(D) The reaction with $HNO_2$ (nitrous acid) depends on the functional group present:$1$. $CH_3CH(CH_3)NO_2$ is a secondary nitroalkane. It reacts with $HNO_2$ to form a pseudonitrole.$2$. $CH_3CH(CH_3)NHCH_3$ is a secondary amine. It reacts with $HNO_2$ to form an $N$-nitrosoamine.$3$. $C_6H_5OH$ (phenol) reacts with $HNO_2$ to form p-nitrosophenol.$4$. $(CH_3)_3CNO_2$ is a tertiary nitroalkane. Tertiary nitroalkanes do not have an $\alpha$-hydrogen atom,which is required for the reaction with $HNO_2$ to form a pseudonitrole. Therefore,it does not react with $HNO_2$.

Which of the following does not react with $HNO_2$?

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