Which is the incorrect observation?

  • A
    For the complex,$[CoF_6]^{3-}$,$F^{-}$ is a weak-field ligand,so that $\Delta_{oct} < P$ (electron-pairing energy) and is thus a high spin complex.
  • B
    For the complex,$[Co(NH_3)_6]^{3+}$,$NH_3$ is a strong-field ligand,so that $\Delta_{oct} > P$ and thus a low spin complex.
  • C
    Stability order: $[Co(H_2O)_6]^{3+} > [Rh(H_2O)_6]^{3+}$
  • D
    Greater the ionic charge on the central metal ion,the greater the value of $\Delta$ $(CFSE)$.

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Compound $PdCl_4 \cdot 6H_2O$ is a hydrated complex; $1 \ m$ aqueous solution of it has a freezing point of $269.28 \ K$. Assuming $100\%$ ionization of the complex,calculate the molecular formula of the complex ($K_f$ for water $= 1.86 \ K \ kg \ mol^{-1}$,freezing point of pure water $= 273 \ K$).

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