Which is not the true statement about $KMnO_4$?

  • A
    Its solution is unstable in acidic medium
  • B
    It gets reduced to $MnO_2$ in neutral medium
  • C
    $MnO_4^-$ changes to $Mn^{+2}$ in basic medium
  • D
    It is self indicator in $Fe^{+2}$ or $C_2O_4^{-2}$ titration

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Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$NaH_{(s)} + H_2O_{(l)} \longrightarrow NaOH_{(aq)} + H_{2(g)} \uparrow$

How do you account for the following observations?
$(a)$ Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants,yet in the manufacture of benzoic acid from toluene,we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.
$(b)$ When concentrated sulphuric acid is added to an inorganic mixture containing chloride,we get a colourless pungent-smelling gas $HCl$,but if the mixture contains bromide,then we get red vapour of bromine. Why?

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$A$ solution of colourless salt $H$ on boiling with excess $NaOH$ produces a non-flammable gas. The gas evolution ceases after sometime. Upon addition of $Zn$ dust to the same solution,the gas evolution restarts. The colourless salt$(s)$ $H$ is (are):

Assign $A, B, C, D$ from the given type of reaction.
$ZnSO_4 \, (aq) + MgCl_2 \, (aq) \longrightarrow$ No reaction

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