Which of the following statements is false?

  • A
    The greater the concentration of the substances involved in a reaction,the lower the speed of the reaction.
  • B
    The point of dynamic equilibrium is reached when the reaction rate in one direction just balances the reaction rate in the opposite direction.
  • C
    The dissociation of a weak electrolyte is a reversible reaction.
  • D
    The presence of free ions facilitates chemical changes.

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For the reaction $H_{2(g)} + I_{2(g)} \rightleftharpoons 2HI_{(g)}$,the value of $K_c$ at $440 \ ^oC$ is $50$. If the reaction is initiated in a $1 \ L$ flask with $1 \ mol$ of $H_2$,$2 \ mol$ of $I_2$,and $3 \ mol$ of $HI$,then the equilibrium concentration of $HI$ will be .......... $M$.

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Consider a reaction that is first order in both directions: $A \underset{K_b}{\stackrel{K_f}{\rightleftharpoons}} B$. Initially only $A$ is present,and its concentration is $A_{0}$. Assume $A_{t}$ and $A_{\text{eq}}$ are the concentrations of $A$ at time $t$ and at equilibrium,respectively. The time $t$ at which $A_{t} = (A_{0} + A_{\text{eq}})/2$ is $....$

$A$ $1 \, M$ solution of glucose reaches dissociation equilibrium according to the equation $C_6H_{12}O_6 \rightleftharpoons 6HCHO$. What is the concentration of $HCHO$ at equilibrium if the equilibrium constant $K_c$ for the formation of glucose from formaldehyde is $6 \times 10^{22}$?

The amount of $PCl_5$ (in moles) that needs to be added to a $1\,L$ vessel at $250\,^oC$ in order to obtain $0.1\,mol$ of $Cl_2$ for the given reaction is:
$PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g)$; $K_C = 0.0414\,mol\,L^{-1}$

The equilibrium constant at $298 \ K$ for a reaction $A + B \rightleftharpoons C + D$ is $100$. If the initial concentration of all the four species were $1 \ M$ each,then the equilibrium concentration of $D$ (in $mol \ L^{-1}$) will be:

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