Which compound does not dissolve in hot dilute $HNO_3$?

$X_2S_n + H_2O \to X(OH)_n \downarrow + Y \uparrow (Gas) \xrightarrow{Pb(CH_3COO)_2} Z \downarrow (Black \ ppt.)$
Then $(X)$ cation can not be

Lead sulfate is soluble in which of the following?

The correct option$(s)$ to distinguish nitrate salts of $Mn^{2+}$ and $Cu^{2+}$ taken separately is (are):
$(A)$ $Mn^{2+}$ shows the characteristic green colour in the flame test
$(B)$ Only $Cu^{2+}$ shows the formation of precipitate by passing $H_2S$ in acidic medium
$(C)$ Only $Mn^{2+}$ shows the formation of precipitate by passing $H_2S$ in faintly basic medium
$(D)$ $Cu^{2+}/Cu$ has higher reduction potential than $Mn^{2+}/Mn$ (measured under similar conditions)

Which of the following is an incorrect match for the precipitate (ppt) and its color?

When $H_2S$ is passed through a solution in $Group-II$ analysis,it sometimes becomes milky. This indicates the presence of: