Which chlorine atom is more electronegative in the following compounds?

  • A
    $CH_3-Cl$
  • B
    $CH_3-CH_2-Cl$
  • C
    $CH_3-CH(CH_3)-Cl$
  • D
    $CH_3-C(CH_3)_2-Cl$

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From the given pairs of compounds,in which will the first compound undergo $S_N2$ reaction faster?

The order of $S_{N^1}$ reactivity in aqueous acetic acid solution for the compounds:
$(1)$ $CH_3-CO-CH_2-Cl$
$(2)$ $CH_3-CH_2-CH_2-Cl$
$(3)$ $(CH_3)_3C-Cl$

$CH_3-CH_2-Cl + NaI \xrightarrow{\text{Acetone}} CH_3-CH_2-I + NaCl$ The above reaction is known as $:-$

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