Which among the following amines has the lowest $pK_{b}$ value?

  • A
    $CH_3CH_2NH_2$
  • B
    $(CH_3CH_2)_2NH$
  • C
    $(CH_3CH_2)_3N$
  • D
    $C_6H_5NH_2$

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Arrange the following in order of their decreasing acidic strength:
$(I)$ $CH_3NH_3^+$
$(II)$ $C_6H_5NH_3^+$
$(III)$ $[H_2N-C(=NH)-NH_2]H^+$
$(IV)$ $O_2N-C_6H_4-NH_3^+$

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Product of the reaction is

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Nitrosobenzene can be prepared by oxidizing aniline with which of the following reagents?

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