Which isomeric amine has the lowest boiling point?

Which statements are True? $A$. In Hoffmann bromamide degradation,$4$ moles of $NaOH$ and $1$ mole of $Br_{2}$ are consumed per mole of an amide. $B$. Hoffmann bromamide reaction is not given by alkyl amides. $C$. Primary amines can be synthesized by Hoffmann bromamide degradation. $D$. Secondary amide on reaction with $Br_{2}$ and $NaOH$ will give secondary amine. $E$. The by-products of Hoffmann degradation are $Na_{2}CO_{3}$,$NaBr$ and $H_{2}O$. Choose the correct answer from the options given below:

Account for the following:
$(i)$ $pK_{b}$ of aniline is more than that of methylamine.
$(ii)$ Ethylamine is soluble in water whereas aniline is not.
$(iii)$ Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
$(iv)$ Although amino group is $o-$ and $p-$ directing in aromatic electrophilic substitution reactions,aniline on nitration gives a substantial amount of $m$-nitroaniline.
$(v)$ Aniline does not undergo Friedel-Crafts reaction.
$(vi)$ Diazonium salts of aromatic amines are more stable than those of aliphatic amines.
$(vii)$ Gabriel phthalimide synthesis is preferred for synthesising primary amines.

The decreasing order of the basic character of the following amines and ammonia is:

In the carbylamine reaction,the number of moles of $KOH$ and $CHCl_3$ used per mole of isocyanide produced are $X_1$ and $X_2$ respectively. Find out $X_1 - X_2$.

The following sequence of reaction on $A$ gives: