Is the splitting of water an exothermic or an endothermic process?

$List-I$ describes thermodynamic processes in four different systems. $List-II$ gives the magnitudes (either exactly or as a close approximation) of possible changes in the internal energy of the system due to the process.

$List-I$	$List-II$
$(I)$ $10^{-3} \, kg$ of water at $100^{\circ} C$ is converted to steam at the same temperature, at a pressure of $10^5 \, Pa$. The volume of the system changes from $10^{-6} \, m^3$ to $10^{-3} \, m^3$. Latent heat of water $= 2250 \, kJ/kg$.	$(P)$ $2 \, kJ$
$(II)$ $0.2 \, moles$ of a rigid diatomic ideal gas with volume $V$ at temperature $500 \, K$ undergoes an isobaric expansion to volume $3V$. Assume $R = 8.0 \, J \, mol^{-1} \, K^{-1}$.	$(Q)$ $7 \, kJ$
$(III)$ One mole of a monatomic ideal gas is compressed adiabatically from volume $V = 1/3 \, m^3$ and pressure $2 \, kPa$ to volume $V/8$.	$(R)$ $4 \, kJ$
$(IV)$ Three moles of a diatomic ideal gas whose molecules can vibrate, is given $9 \, kJ$ of heat and undergoes isobaric expansion.	$(S)$ $5 \, kJ$
	$(T)$ $3 \, kJ$

Which one of the following options is correct?

One mole of an ideal monoatomic gas is heated at a constant pressure of one atmosphere from $0^{\circ}C$ to $100^{\circ}C$. Then the change in the internal energy is

$A$ gas is compressed from a volume of $2\,m^3$ to a volume of $1\,m^3$ at a constant pressure of $100\,N/m^2$. Then it is heated at constant volume by supplying $150\,J$ of energy. As a result,the internal energy of the gas

Two gases $A$ and $B$ are filled at the same pressure in separate cylinders with movable pistons of radius $r_A$ and $r_B$,respectively. On supplying an equal amount of heat to both the systems reversibly under constant pressure,the pistons of gas $A$ and $B$ are displaced by $16 \ cm$ and $9 \ cm$,respectively. If the change in their internal energy is the same,then the ratio $\frac{r_A}{r_B}$ is equal to

$P-V$ diagram of a cyclic process $ABCA$ is as shown in figure. Choose the correct statement.