When an aqueous solution of borax is acidified with hydrochloric acid,a white crystalline solid is formed which is soapy to touch. Is this solid acidic or basic in nature? Explain.

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(N/A) An aqueous solution of borax is acidified with $HCl$ to produce boric acid $(H_{3}BO_{3})$,which appears as a white crystalline solid and is soapy to the touch.
The chemical reaction is:
$Na_{2}B_{4}O_{7} + 2HCl + 5H_{2}O \rightarrow 2NaCl + 4H_{3}BO_{3}$
This solid is acidic in nature. Boric acid is a weak monobasic Lewis acid. It does not act as a protonic acid (it does not release $H^{+}$ ions directly); instead,it acts as a Lewis acid by accepting a lone pair of electrons from a hydroxyl ion $(OH^{-})$ from water:
$B(OH)_{3} + 2H_{2}O \rightarrow [B(OH)_{4}]^{-} + H_{3}O^{+}$

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Similar Questions

Identify the correct statements from the following:
$i$. $H_3BO_3$ is a monobasic acid.
$ii$. The correct formula of borax is $Na_2[B_4O_5(OH)_4] \cdot 8H_2O$.
$iii$. $NaBH_4$ is a reducing agent.

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