When aniline reacts with $NaNO_2$ and dil. $HCl$ at $0^{\circ} - 5^{\circ}C,$ the product formed is

  • A
    Nitroaniline
  • B
    Benzene diazonium chloride
  • C
    Benzene
  • D
    Trinitroaniline

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Aniline reacts with mixed acid (conc. $HNO_3$ and conc. $H_2SO_4$) at $288 \ K$ to give $P$ $(51 \%)$,$Q$ $(47 \%)$ and $R$ $(2 \%)$. The major product$(s)$ of the following reaction sequence is (are):
$R$ $\xrightarrow[2) Br_2, CH_3CO_2H]{1) Ac_2O, \text{pyridine}}$ $\xrightarrow{3) H_3O^+}$ $\xrightarrow{4) NaNO_2, HCl / 273-278 \ K}$ $\xrightarrow{5) EtOH, \Delta}$ $\xrightarrow{6) Sn/HCl}$ $\xrightarrow{7) Br_2/H_2O \text{ (excess)}} \text{Major Product}$

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