Vapour pressures of pure liquids $A$ and $B$ are $300$ and $800 \ torr$ respectively at $25^{\circ}C$. When these two liquids are mixed at this temperature to form a solution in which mole percentage of $B$ is $90$,the total vapour pressure is observed to be $720 \ torr$. Which of the following is true for this solution?

  • A
    $\Delta V_{\text{mix}} > 0$
  • B
    $\Delta H_{\text{mix}} < 0$
  • C
    $\Delta V_{\text{mix}} = 0$
  • D
    $\Delta S_{\text{mix}} < 0$

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Assuming the formation of an ideal solution,determine the boiling point of a mixture containing $1560 \ g$ benzene (molar mass $= 78 \ g/mol$) and $1125 \ g$ chlorobenzene (molar mass $= 112.5 \ g/mol$) against an external pressure of $1000 \ torr$ using the provided graph. (in $^{\circ}C$)

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