The transition metal used as a catalyst is

Identify the correct statement$(s)$ among the following.

Identify the correct option:
$(I)\ AgCl$ is not soluble in $H_2O$ but soluble in $KCN$.
$(II)\ Zn$ when reacts with cold v.v. dil $HNO_3$ gives $NH_4NO_3$.
$(III)\ CuSO_4$ reacts with $KI$ to form $Cu_2I_2 + K_2SO_4$.
$(IV)\ CuSO_4 \cdot 5H_2O \xrightarrow{1000\,^oC}$ The gases liberated are $SO_2$ and $O_2$.

Match the following properties with the corresponding metals:

Property	Metal
$a$. Element with highest second ionization enthalpy $(\Delta_{i} H_2)$	$i$. $Co$
$b$. Element with highest third ionization enthalpy $(\Delta_{i} H_3)$	$ii$. $Cr$
$c$. $M$ in $[M(CO)_6]$	$iii$. $Cu$
$d$. Element with highest heat of atomization $(\Delta_{a} H)$	$iv$. $Zn$
	$v$. $Ni$

Statement $(I)$ $Co^{2+}$ has a higher magnetic moment than $Cr^{3+}$.
Statement $(II)$ Ionisation enthalpies of $Ce$,$Pr$ and $Nd$ are higher than $Th$,$Pa$ and $U$.
Which of the following is correct?

Which of the comparison regarding $Zn, Cd, Hg$ is/are incorrect?
$(I)$ $ZnCl_2$ is ionic whereas $CdCl_2$ and $HgCl_2$ are covalent
$(II)$ $Zn$ and $Cd$ dissolve in dilute acid $(HCl)$ liberating $H_2$ but $Hg$ cannot
$(III)$ $Zn$ and $Cd$ form white ppt. of $Zn(OH)_2$ and $Cd(OH)_2$ but $Hg$ forms coloured ppt. of $HgO$ or $Hg(OH)_2$
$(IV)$ All form $M_2^{2+}$ type ion