The temperature dependence of the rate constant $(k)$ of a chemical reaction is expressed by the Arrhenius equation,$k = A \cdot e^{-E^*/RT}$. The activation energy $(E^*)$ of the reaction can be calculated by plotting:

  • A
    $\log \, k$ vs $\frac{1}{T}$
  • B
    $k$ vs $T$
  • C
    $k$ vs $\frac{1}{\log \, T}$
  • D
    $\log \, k$ vs $T$

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The activation energy for a reaction is $9.0 \, kcal/mol$. The increase in the rate constant when its temperature is increased from $298 \, K$ to $308 \, K$ is $......... \, \%$.

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The following figure shows a graph of $\log_{10}K$ vs $\frac{1}{T}$,where $K$ is the rate constant and $T$ is the temperature. The straight line $BC$ has a slope,$\tan \theta = -\frac{1}{2.303}$,and an intercept of $5$ on the $Y$-axis. Thus,$E_a$,the energy of activation,is ....... $cal$.

Reactant $A$ shows two reactions:
$A \xrightarrow{K_1} B$,activation energy $= Ea_1$
$A \xrightarrow{K_2} C$,activation energy $= Ea_2$
If $Ea_1 = \frac{Ea_2}{3}$,then the relation between $K_1$ and $K_2$ is:

If for a hypothetical reaction,$E_a = 0$ at $273 \ K$,then find the ratio of the rate constants at $383 \ K$ and $273 \ K$.

Consider a complex reaction taking place in three steps with rate constants $k_1$,$k_2$,and $k_3$ respectively. The overall rate constant $k$ is given by the expression $k = \sqrt{\frac{k_1 k_3}{k_2}}$. If the activation energies of the three steps are $60$,$30$,and $10 \ kJ \ mol^{-1}$ respectively,then the overall energy of activation in $kJ \ mol^{-1}$ is $..........$ $(Nearest \ integer)$

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