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In the given pair of compounds,in which pair does the second compound have a higher boiling point than the first compound?

The reaction given below is known as:
$ArN_2^+ X^- + Cu_2Cl_2 + HCl \to ArCl + N_2 + Cu_2Cl_2$

Reduction of nitroalkanes in neutral medium (e.g.,$Zn / NH_4Cl$) forms mainly

Which one of the following compounds undergoes bromination of its aromatic ring (electrophilic aromatic substitution) at the fastest rate?

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The major product in the following reaction is:

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