The standard reduction potential data at $25^{\circ} C$ is given below.
$E^{\circ}(Fe^{3+}, Fe^{2+}) = +0.77 \ V$
$E^{\circ}(Fe^{2+}, Fe) = -0.44 \ V$
$E^{\circ}(Cu^{2+}, Cu) = +0.34 \ V$
$E^{\circ}(Cu^{+}, Cu) = +0.52 \ V$
$E^{\circ}(O_{2(g)} + 4H^{+} + 4e^{-} \rightarrow 2H_{2}O) = +1.23 \ V$
$E^{\circ}(O_{2(g)} + 2H_{2}O + 4e^{-} \rightarrow 4OH^{-}) = +0.40 \ V$
$E^{\circ}(Cr^{3+}, Cr) = -0.74 \ V$
$E^{\circ}(Cr^{2+}, Cr) = -0.91 \ V$
Match $E^{\circ}$ of the redox pair in List-$I$ with the values given in List-$II$ and select the correct answer using the code given below the lists:
List-$I$ List-$II$
$P. \ E^{\circ}(Fe^{3+}, Fe)$ $1. \ -0.18 \ V$
$Q. \ E^{\circ}(4H_{2}O \rightleftharpoons 4H^{+} + 4OH^{-})$ $2. \ -0.4 \ V$
$R. \ E^{\circ}(Cu^{2+} + Cu \rightarrow 2Cu^{+})$ $3. \ -0.04 \ V$
$S. \ E^{\circ}(Cr^{3+}, Cr^{2+})$ $4. \ -0.83 \ V$

Codes: $P \quad Q \quad R \quad S$

  • A
    $4 \quad 1 \quad 2 \quad 3$
  • B
    $2 \quad 3 \quad 4 \quad 1$
  • C
    $1 \quad 2 \quad 3 \quad 4$
  • D
    $3 \quad 4 \quad 1 \quad 2$

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