The solution of sugar in water contains

The osmotic pressure of $0.1 \ M$ monobasic acid of $pH \ 3$ at $27^{\circ} C$ is (in $atm$)

The elevation in the boiling point of an aqueous urea solution is $0.104 \ K$. What is its $\Delta T_{f}$ (in $K$) value? (Given for water: $K_{b} = 0.52 \ K \ kg \ mol^{-1}$,$K_{f} = 1.86 \ K \ kg \ mol^{-1}$)

Which one of the following statements is false?

Assertion : If one component of a solution obeys Raoult's law over a certain range of composition,the other component will not obey Henry's law in that range.
Reason : Raoult's law is a special case of Henry's law.

$2.5 \ g$ of a non-volatile,non-electrolyte is dissolved in $100 \ g$ of water at $25^{\circ} C$. The solution showed a boiling point elevation by $2^{\circ} C$. Assuming the solute concentration is negligible with respect to the solvent concentration,the vapour pressure of the resulting aqueous solution is . . . . . . $mm$ of $Hg$ (nearest integer).
[Given : Molal boiling point elevation constant of water $(K_b) = 0.52 \ K \ kg \ mol^{-1}$,
$1 \ atm$ pressure $= 760 \ mm$ of $Hg$,molar mass of water $= 18 \ g \ mol^{-1}]$