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Which of the following orders is not correct about the property shown against it?

To which block do the elements with the following outer electronic configurations belong?
$(i)$ $6s^2 4f^3$
$(ii)$ $3s^2 3p^4$
$(iii)$ $3s^1$
$(iv)$ $3d^2 4s^2$

The number of the following pairs of elements which exhibit a diagonal relationship is:
$1. B \text{ and } Si$
$2. Be \text{ and } Al$
$3. Li \text{ and } Mg$
$4. Al \text{ and } S$

Outermost electronic configuration of a group $13$ element,$E$,is $4s^2 4p^1$. The electronic configuration of an element of $p$-block,period $5$,placed diagonally to element $E$ is:

Select the correct statements from the following:
$(a)$ Effective nuclear charge for nitrogen is $3.90$
$(b)$ $IP$ of $Ne$ is more than $Na^{+}$
$(c)$ Order of electronegativity $sp > sp^2 > sp^3$
$(d)$ Order of acidic character $NH_3 < PH_3 < AsH_3$

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