The reaction $1/2 H_{2(g)} + AgCl_{(s)} \to H^{+}_{(aq)} + Cl^{-}_{(aq)} + Ag_{(s)}$ occurs in the galvanic cell:

Using the standard electrode potentials given in Table $3.1$ of the $NCERT$ textbook,predict if the reaction between the following is feasible:
$(i)$ $Fe^{3+}_{(aq)}$ and $I^{-}_{(aq)}$
$(ii)$ $Ag^{+}_{(aq)}$ and $Cu_{(s)}$
$(iii)$ $Fe^{3+}_{(aq)}$ and $Br^{-}_{(aq)}$
$(iv)$ $Ag_{(s)}$ and $Fe^{3+}_{(aq)}$
$(v)$ $Br_{2(aq)}$ and $Fe^{2+}_{(aq)}$

An electrochemical cell can behave like an electrolytic cell when . . . . . . .

Copper cannot replace $.....$ from its solution.

For the electrochemical cell,$M|M^{+}||X^{-}|X,$ given $E^{\circ}(M^{+}|M) = 0.44 \; V$ and $E^{\circ}(X|X^{-}) = 0.33 \; V$. From this data,one can deduce that:

Fill in the blanks :
$(1)$ In a galvanic cell,the anode and cathode possess $\dots$ and $\dots$ charge respectively.
$(2)$ According to convention,the anode and cathode in a galvanic cell are present on the $\dots$ and $\dots$ side respectively.