The rate constant of a reaction depends upon

For a first order reaction,the rate of reaction is $2.4 \times 10^{-3} \ mol \ L^{-1} \ s^{-1}$ at $27 \ ^\circ C$. The activation energy of the reaction is $24.942 \ kJ \ mol^{-1}$. The rate of reaction at $327 \ ^\circ C$ is ....... $mol \ L^{-1} \ s^{-1}$ [Take $e^5 = 150$,$e^{0.005} = 1$,$e^4 = 55$].

Reactant $A$ converts to product $D$ through the given mechanism (with the net evolution of heat) :

$A \rightarrow B$	$slow ; \Delta H=+ve$
$B \rightarrow C$	$fast ; \Delta H=-ve$
$C \rightarrow D$	$fast ; \Delta H=-ve$

Which of the following represents the above reaction mechanism ?

Subtract $(i)$ $\ln \, k_1 = - \frac{E_a}{R T_1} + \ln A$ and $(ii)$ $\ln \, k_2 = - \frac{E_a}{R T_2} + \ln A$ and write the resulting equation.

Define the following terms:
$1.$ Collision
$2.$ Frequency of collision

If we plot a graph between $\log \, K$ and $\frac{1}{T}$ by Arrhenius equation,the slope is