The potential for the given half cell at $298 \ K$ is $(-) \ldots \ldots \ldots \times 10^{-2} \ V.$
$2 H^{+}_{(aq)} + 2 e^- \rightarrow H_{2(g)}$
$[H^{+}] = 1 \ M, P_{H_2} = 2 \ atm$
(Given: $2.303 RT / F = 0.06 \ V, \log 2 = 0.3$)

  • A
    $0$
  • B
    $1$
  • C
    $3$
  • D
    $4$

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Fill in the blanks :
$1.$ The ratio of concentration of products to concentration of reactants is ........
$2.$ $\ln(\log(x)) =$ ............
$3.$ At equilibrium,between $E_{cell}$ and $E_{cell}^{o}$,......... will be zero.

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Which of the following relations represents the correct relation between standard electrode potential and equilibrium constant?
$I$. $\log K = \frac{nF E^o}{2.303 RT}$
$II$. $K = e^{\frac{nF E^o}{RT}}$
$III$. $\log K = -\frac{nF E^o}{2.303 RT}$
$IV$. $\log K = 0.4342 \frac{nF E^o}{RT}$
Choose the correct statement$(s)$.

The magnitude of the change in oxidising power of the $MnO_4^- / Mn^{2+}$ couple is $x \times 10^{-4} \, V$,if the $H^{+}$ concentration is decreased from $1 \, M$ to $10^{-4} \, M$ at $25^{\circ} C$. (Assume concentration of $MnO_4^-$ and $Mn^{2+}$ to be same on change in $H^{+}$ concentration). The value of $x$ is ....... .
(Rounded off to the nearest integer)
$[\text{Given} : \frac{2.303 RT}{F} = 0.059]$

Calculate the cell potential at $298 \ K$ for the following cell:
$Zn_{(s)} | Zn^{2+} (0.6 \ M) || Cu^{2+} (0.3 \ M) | Cu_{(s)} \quad [E_{cell}^{o} = 1.1 \ V]$

Write the Nernst equation for the $E_{cell}$ reaction in the Daniell cell. How will the $E_{cell}$ be affected when the concentration of $Zn^{2+}$ ions is increased?

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