The oxidation of benzyl chloride with lead nitrate gives

  • A
    Benzyl alcohol
  • B
    Benzoic acid
  • C
    Benzaldehyde
  • D
    $p-$chlorobenzaldehyde

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Which of the following catalysts is used in the Rosenmund reaction?

Identify the compound $C$ in the following sequence:
$(CH_3)_2CHCH_2C \equiv N$ $\xrightarrow{HCl, H_2O} \text{compound } A$ $\xrightarrow[2. H_2O]{1. LiAlH_4} \text{compound } B$ $\xrightarrow{PCC, CH_2Cl_2} \text{compound } C$

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Write the structures of products of the following reactions:
$(i)$ Benzene + $C_{2}H_{5}COCl$ $\xrightarrow{\text{Anhyd. } AlCl_{3}, CS_{2}}$
$(ii)$ $(C_{6}H_{5}CH_{2})_{2}Cd + 2 CH_{3}COCl \rightarrow$
$(iii)$ $H_{3}C - C \equiv C - H$ $\xrightarrow{Hg^{2+}, H_{2}SO_{4}}$
$(iv)$ $p$-Nitrotoluene $\xrightarrow{1. CrO_{2}Cl_{2}, 2. H_{3}O^{+}}$

Match the reactants in column $-I$ with the reaction conditions in column $-II$ to find the corresponding products in column $-III$.
Column $-I$ (Reactant) Column $-II$ (Reaction Condition) Column $-III$ (Product)
$A$. $CH_3CN + C_6H_5MgBr$ $i$. $Ether, H_3O^+$ $p$. Benzaldehyde
$B$. $Benzene + CH_3COCl$ $ii$. $Hg^{2+}, H_2SO_4, H_2O$ $q$. Acetophenone
$C$. $Toluene$ $iii$. $Anhydrous AlCl_3$ $r$. Propiophenone
$D$. $Phenyl ethyne$ $iv$. $x. Cl_2, hv$; $y. H_2O, 373 \ K$ $s$. Acetaldehyde

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Acetic acid is treated with $Ca(OH)_2$ and the product so obtained is subjected to dry distillation. The final product is

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