The most reactive compound towards nucleophilic substitution with an aqueous $NaOH$ is

For the reaction shown below,identify the major product $A$ and the reaction mechanism $R$:
$m$-bromoanisole $\xrightarrow{NaNH_2} A, R$

Nitrobenzene on further excessive nitration gives

Which of the following are deactivating groups?
$-OH, -COCH_3, -NO_2, -NH_2, -Cl, -Br, -NHCOCH_3, -COOH$

Given below are two statements:
Statement $I$: Benzene is nitrated to give nitrobenzene,which on further treatment with $CH_{3}COCl / AlCl_{3}$ will give the product shown in the image.
Statement $II$: $NO_{2}$ group is a $m$-directing and deactivating group.
In the light of the above statements,choose the most appropriate answer:

Which of the following sets of compounds is $NOT$ arranged in the order of decreasing reactivity towards electrophilic aromatic substitution?