The melting point of $AlF_3$ is $1040 \, ^{\circ}C$ and that of $SiF_4$ is $-77 \, ^{\circ}C$ (it sublimes) because

  • A
    there is a very large difference in the ionic character of the $Al-F$ and $Si-F$ bond
  • B
    in $AlF_3$,$Al^{3+}$ interacts very strongly with the neighbouring $F^{-}$ ions to give a three-dimensional structure,but in $SiF_4$ no such interaction is possible
  • C
    The silicon ion in the tetrahedral $SiF_4$ molecule is not shielded effectively from the fluoride ions,whereas in $AlF_3$,the $Al^{3+}$ ion is shielded on all sides
  • D
    the attractive forces between the $SiF_4$ molecules are strong,whereas those between the $AlF_3$ molecules are weak

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