The major product obtained in the reaction of isobutylbenzene with acetic anhydride in the presence of anhydrous $AlCl_3$ is:

  • A
    $p-$isobutylacetophenone
  • B
    acetophenone
  • C
    $m-$isobutylacetophenone
  • D
    $o-$isobutylacetophenone

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Rosenmund reduction cannot be used for the preparation of

An organic compound $X$ gives a red precipitate on heating with Fehling's solution. Which one of the following reactions yields $X$ as a major product?

In column - $I$ reaction name,in column - $II$ reactant and in column - $III$ product are given,match column - $I$ with column - $II$ and column - $III$ with the correct option.
Column - $I$ and $II$ Column - $III$
$(A).$ Rosenmund reaction - $(i).$ $H_2, Pd, BaSO_4$ $(p).$ Benzene to benzaldehyde
$(B).$ Stephen reaction - $(iii).$ $SnCl_2, HCl$ $(q).$ Benzoyl chloride to benzaldehyde
$(C).$ Etard reaction - $(iv).$ $CrO_2Cl_2, CS_2$ $(r).$ Toluene to chromium complex
$(D).$ Gatterman-Koch reaction - $(ii).$ $CO, HCl$ anhydrous $AlCl_3/CuCl$ $(s).$ $RCN \to RCHO$

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What is $(P)$ in the reaction given below?
$(P)$ $\xrightarrow[\text{(ii) } H_3O^{+}]{\text{(i) } CH_3MgBr} (R)$ $\xrightarrow[\text{(ii) } \Delta]{\text{(i) dil. } NaOH} \text{4-methylpent-3-en-2-one}$

Which of the following reactions will not produce acetaldehyde?

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