The main constituent of biogas is

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(B) Biogas is a mixture of gases produced by the breakdown of organic matter in the absence of oxygen (anaerobic digestion).It primarily consists of $

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methane

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(B) Biogas is a mixture of gases produced by the breakdown of organic matter in the absence of oxygen (anaerobic digestion).It primarily consists of $CH_4$ (methane),which typically accounts for $50-75\%$ of the total volume.Other components include $CO_2$ (carbon dioxide),$H_2$ (hydrogen),and $H_2S$ (hydrogen sulphide) in smaller quantities.Therefore,methane is the main constituent of biogas.

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