The hydrolysis of an ester was carried out separately with $0.1 \ N$ $HCl$ and $0.1 \ N$ $H_2SO_4$. Then for the rate of reaction $(R)$ in the presence of acid,which of the following relations is true?

  • A
    $R_{HCl} > R_{H_2SO_4}$
  • B
    $R_{HCl} < R_{H_2SO_4}$
  • C
    $R_{HCl} = \frac{1}{2} R_{H_2SO_4}$
  • D
    $R_{HCl} = R_{H_2SO_4}$

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$A$ substance $S$ undergoes two reactions under similar reaction conditions:
$\mathop S\limits_{(2.0 \ M)} \xrightarrow{K_0} X$ (zero order)
$\mathop S\limits_{(2.0 \ M)} \xrightarrow{K_2} Y$ (second order)
The time taken for the concentration of $S$ to become half is $40 \ s$ and $10 \ s$ for the zero-order and second-order reactions,respectively. What is the value of the ratio $K_0 / K_2$?

The rate constant for the first order decomposition of $H_{2}O_{2}$ is given by the following equation:
$\log k = 14.34 - 1.25 \times 10^{4} \, K / T$
Calculate $E_{a}$ for this reaction and at what temperature will its half-period be $256 \, min$?

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Select the incorrect statement.

Which one of the following represents a complex reaction?

Under the same reaction conditions,initial concentration of $1.386 \ mol \ dm^{-3}$ of a substance becomes half in $40 \ s$ and $20 \ s$ through first order and zero order kinetics,respectively. The ratio $\left(\frac{k_1}{k_0}\right)$ of the rate constants for first order $\left(k_1\right)$ and zero order $\left(k_0\right)$ of the reactions is:

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