The hydrogen electrode is dipped in a solution of $pH=3$ at $25^{\circ} C$. The potential of the electrode will be . . . . . . $\times 10^{-2} \ V$. $\left(\frac{2.303 RT}{F}=0.059 \ V\right)$

  • A
    $30$
  • B
    $75$
  • C
    $45$
  • D
    $-17.7$

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The change in electrode potential of $Cr^{3+}/Cr_2O_7^{2-}$ electrode at $25 \ ^oC$ due to change in $pH$ of its electrolytic solution from $1$ to $3$ is ........... $V$ (Assume: $[Cr_2O_7^{2-}]$ and $[Cr^{3+}]$ remain constant). Use: $\frac{2.303RT}{F} = 0.06$.

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In a cell,a copper electrode was used as a cathode. What is the electrode potential (in $V$) of the copper electrode dipped in $0.1 \ M \ Cu^{2+}$ solution at $298 \ K$?
$(E_{Cu^{2+}/Cu}^{\ominus} = 0.34 \ V; \frac{2.303 \ RT}{F} = 0.06 \ V)$

In an electrochemical reaction of lead,at standard temperature,if $E^0_{(Pb^{2+}/Pb)} = m \ V$ and $E^0_{(Pb^{4+}/Pb)} = n \ V$,then the value of $E^0_{(Pb^{2+}/Pb^{4+})}$ is given by $m - x n$. The value of $x$ is $...........$. (Nearest integer)

For the electrochemical cell,$Mg_{(s)} \mid Mg^{2+}(aq, 1 \ M) \parallel Cu^{2+}(aq, 1 \ M) \mid Cu_{(s)}$,the standard emf of the cell is $2.70 \ V$ at $300 \ K$. When the concentration of $Mg^{2+}$ is changed to $x$,the cell potential changes to $2.67 \ V$ at $300 \ K$. The value of $x$ is.
(Given: $\frac{F}{R} = 11500 \ K \ V^{-1}$,where $F$ is the Faraday constant and $R$ is the gas constant; $\ln(10) = 2.30$)

Under which of the following conditions is the $E$ value of the cell for the given reaction maximum?
$Zn_{(s)} + Cu^{2+}_{(aq)} \rightleftharpoons Cu_{(s)} + Zn^{2+}_{(aq)}$
$\left( \frac{2.303 RT}{F} \text{ at } 298 \ K = 0.059 \ V, E^{\circ}_{Zn^{2+}/Zn} = -0.76 \ V, E^{\circ}_{Cu^{2+}/Cu} = +0.34 \ V \right)$
Let $[Zn^{2+}] = C_2$ and $[Cu^{2+}] = C_1$.

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