The heat liberated when $1.89 \ g$ of benzoic acid is burnt in a bomb calorimeter at $25^{\circ} C$ increases the temperature of $18.94 \ kg$ of water by $0.632^{\circ} C$. If the specific heat of water at $25^{\circ} C$ is $0.998 \ cal / (g^{\circ} C)$,then find the heat of combustion of benzoic acid.
- A$2540 \ kJ \ mol^{-1}$
- B$1975 \ kJ \ mol^{-1}$
- C$3240 \ kJ \ mol^{-1}$
- D$2825 \ kJ \ mol^{-1}$
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For the reaction $2X_{(g)} + Y_{(g)} \to 2Z_{(g)}$ at $298 \ K$,$\Delta U = -10.5 \ kJ$ and $\Delta S^o = -10.5 \ J/K$. Calculate $\Delta G^o$ for the reaction. Will the reaction be spontaneous or not? Explain.
Difficult
View SolutionFor the reaction $\frac{1}{2}X_2 + \frac{3}{2}Y_2 \to XY_3$,$\Delta H = -30 \ kJ/mol$. Given $\Delta S_{X_2} = 60 \ J/mol \cdot K$,$\Delta S_{Y_2} = 40 \ J/mol \cdot K$,and $\Delta S_{XY_3} = 50 \ J/mol \cdot K$,calculate the temperature at equilibrium in $K$.
Difficult
View SolutionIdentify the correct statements from the following.
$I$. At $0 \ K$,the entropy of pure crystalline materials approaches zero.
$II$. Entropy for the process,$H_2O_{(l)} \longrightarrow H_2O_{(g)}$ decreases.
$III$. Gibbs' energy is a state function.
$I$. At $0 \ K$,the entropy of pure crystalline materials approaches zero.
$II$. Entropy for the process,$H_2O_{(l)} \longrightarrow H_2O_{(g)}$ decreases.
$III$. Gibbs' energy is a state function.
The reaction of cyanamide,$NH_2CN_{(s)}$,with dioxygen was carried out in a bomb calorimeter,and $\Delta U$ was found to be $-742.7 \ kJ \ mol^{-1}$ at $298 \ K$. Calculate the enthalpy change for the reaction at $298 \ K$.
$NH_2CN_{(s)} + \frac{3}{2}O_{2_{(g)}} \to N_{2_{(g)}} + CO_{2_{(g)}} + H_2O_{(l)}$
$NH_2CN_{(s)} + \frac{3}{2}O_{2_{(g)}} \to N_{2_{(g)}} + CO_{2_{(g)}} + H_2O_{(l)}$
Medium
View Solution$500 \ J$ of energy is transferred as heat to $0.5 \ mol$ of Argon gas at $298 \ K$ and $1.00 \ atm$. The final temperature and the change in internal energy respectively are $:$ Given $: R = 8.3 \ J \ K^{-1} \ mol^{-1}$
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