The enthalpy of combustion of ${C_6H_6}_{(l)}$ is $-3250 \, kJ/mol$. When $0.39 \, g$ of benzene is burnt in excess of oxygen in an open vessel,the amount of heat evolved is:

Comment on the thermodynamic stability of $NO_{(g)}$,given:
$\frac{1}{2} N_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{(g)}; \Delta_r H^{\ominus} = 90 \, kJ \, mol^{-1}$
$NO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{2(g)}; \Delta_r H^{\ominus} = -74 \, kJ \, mol^{-1}$

Based on the following thermochemical equations,find the value of $x$ in $kJ$.
$(i) \ H_2O_{(g)} + C_{(s)} \to CO_{(g)} + H_{2(g)} ; \Delta H = 131 \ kJ$
$(ii) \ CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)} ; \Delta H = -282 \ kJ$
$(iii) \ H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(g)} ; \Delta H = -242 \ kJ$
$(iv) \ C_{(s)} + O_{2(g)} \to CO_{2(g)} ; \Delta H = -x \ kJ$

If the bond formation energy of the $H-H$ bond is $-433 \ kJ \ mol^{-1}$,find the bond dissociation energy for $0.5 \ mol$ of $H_{2(g)}$. (in $kJ$)

$H_{2(g)} + \frac{1}{2}O_{2(g)} \rightarrow H_2O_{(l)}$; $\Delta H_{298K} = -68.32 \, kcal$. The enthalpy of vaporization of water at $25 \, ^\circ C$ and $1 \, atm$ pressure is $10.52 \, kcal$. Calculate the standard enthalpy of formation of $1 \, mole$ of water vapor at $25 \, ^\circ C$ (in $kcal$).

Calculate the standard enthalpy change of the following reaction: $CH_{4(g)} + 2O_{2(g)} \rightarrow CO_{2(g)} + 2H_{2}O_{(\ell)}$ if $\Delta_{f} H^{\circ}(CH_{4}) = -75 \ kJ \ mol^{-1}$,$\Delta_{f} H^{\circ}(CO_{2}) = -390 \ kJ \ mol^{-1}$,and $\Delta_{f} H^{\circ}(H_{2}O) = -286 \ kJ \ mol^{-1}$.