The drain cleaner,Drainex contains small bits of aluminum which react with caustic soda to produce dihydrogen. What volume of dihydrogen at $20^{\circ} C$ and $1 \, bar$ will be released when $0.15 \, g$ of aluminum reacts?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(D) The reaction of aluminum with caustic soda is given by:
$2Al(s) + 2NaOH(aq) + 2H_2O(l) \to 2NaAlO_2(aq) + 3H_2(g)$
From the stoichiometry,$2 \, mol$ of $Al$ $(54 \, g)$ produces $3 \, mol$ of $H_2$.
At $STP$ ($273.15 \, K$ and $1 \, bar$),$1 \, mol$ of an ideal gas occupies $22.7 \, L$ $(22700 \, mL)$.
Volume of $H_2$ at $STP$ produced by $0.15 \, g$ of $Al$:
$V_{STP} = \frac{3 \times 22700 \times 0.15}{54} \, mL = 189.17 \, mL$
Using the combined gas law $\frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2}$:
$P_1 = 1 \, bar, V_1 = 189.17 \, mL, T_1 = 273.15 \, K$
$P_2 = 1 \, bar, T_2 = 293.15 \, K$
$V_2 = \frac{P_1 V_1 T_2}{P_2 T_1} = \frac{1 \times 189.17 \times 293.15}{1 \times 273.15} \approx 203 \, mL$
Thus,$203 \, mL$ of dihydrogen is released.

Explore More

Similar Questions

To a $25 \, mL$ of $H_2O_2$ solution,an excess of acidified solution of $KI$ was mixed. The liberated $I_2$ required $20 \, mL$ of $0.3 \, M$ hypo $(Na_2S_2O_3)$ solution for neutralization. The volume strength of $H_2O_2$ is......$mL$.

For the complete combustion of $1 \, mol$ of a compound with the molecular formula $C_xH_yO_z$,the number of moles of $O_2$ required is:

To $50 \ mL$ of $0.1 \ N \ Na_2CO_3$ solution,$150 \ mL$ of water is added. What is the molarity of the resultant solution?

$x \ mg$ of pure $HCl$ was used to make an aqueous solution. $25.0 \ mL$ of $0.1 \ M$ $Ba(OH)_2$ solution is used when the $HCl$ solution was titrated against it. The numerical value of $x$ is . . . . . . $\times 10^{-1}$. (Nearest integer)
Given: Molar mass of $HCl$ and $Ba(OH)_2$ are $36.5$ and $171.0 \ g \ mol^{-1}$ respectively.

$A$ flask is weighed when filled with methane $(CH_4)$. The methane is then removed,and the flask is weighed again. When the flask is filled with oxygen $(O_2)$ at the same temperature and pressure,the mass of oxygen will be:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo