The correct option$(s)$ regarding the complex $[Co(en)(NH_3)_3(H_2O)]^{3+}$ $(en = H_2NCH_2CH_2NH_2)$ is (are):
$A$. It has two geometrical isomers
$B$. It will have three geometrical isomers if bidentate 'en' is replaced by two cyanide ligands
$C$. It is paramagnetic
$D$. It absorbs light at longer wavelength as compared to $[Co(en)(NH_3)_4]^{3+}$

  • A
    $A, B, D$
  • B
    $A, B, C$
  • C
    $A, B$
  • D
    $B, D$

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Match the following:
Column-$1$ (Reaction)Column-$2$ (Main product)
$A$. $4FeCl_3 + 3K_4[Fe(CN)_6] \rightarrow$$I$. $Fe_4[Fe(CN)_6]_3$
$B$. $ZnCl_2 + 4NaOH \rightarrow$$V$. $Na_2ZnO_2$
$C$. $2FeCl_3 + H_2S \rightarrow$$II$. $FeCl_2$

$A$ mixture $X$ containing $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ is dissolved in water to make a $2 \, L$ solution.
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
$1 \, L \, of \, X + \text{Excess of } BaCl_2 \rightarrow Z \, mol \, of \, ppt.$
Then $Y$ and $Z$ are respectively ...............

Give the correct order of initials $T$ or $F$ for following statements. Use $T$ if statement is true and $F$ if it is false.
$(I)$ Sulphide ions react with $Na_2[Fe(CN)_5(NO)]$ to form a purple coloured compound $Na_4[Fe(CN)_5(NOS)]$. In the reaction,the oxidation state of iron changes.
$(II)$ $Pt(IV)$ compounds are relatively more stable than $Ni(IV)$ compounds.
$(III)$ The welding of magnesium can be done in the atmosphere of Helium.
$(IV)$ $LiAlH_4$ on hydrolysis will give $H_2$.

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Which of the given statements is incorrect?

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The correct option(s) about entropy $(S)$ is(are)
$[R =$ gas constant, $F =$ Faraday constant, $T =$ Temperature $]$
$(A)$ For the reaction, $M_{(s)} + 2H^{+}_{(aq)} \rightarrow H_{2(g)} + M^{2+}_{(aq)}$, if $\frac{dE_{cell}}{dT} = \frac{R}{F}$, then the entropy change of the reaction is $R$ (assume that entropy and internal energy changes in entropy and internal energy are temperature independent).
$(B)$ The cell reaction, $Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 0.01 \ M) \parallel H^{+}(aq, 0.1 \ M) \mid H_2(g, 1 \ bar) \mid Pt_{(s)}$, is an entropy driven process.
$(C)$ For racemization of an optically active compound, $\Delta S > 0$.
$(D)$ $\Delta S > 0$, for $[Ni(H_2O)_6]^{2+} + 3en \rightarrow [Ni(en)_3]^{2+} + 6H_2O$ (where $en =$ ethylenediamine).

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