(B) The bond between $P$ and $Cl$ in $PCl_5$ is primarily covalent due to the electronegativity difference between $P$ $(2.19)$ and $Cl$ $(3.16)$.Sinc

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Covalent with some ionic character

(B) The bond between $P$ and $Cl$ in $PCl_5$ is primarily covalent due to the electronegativity difference between $P$ $(2.19)$ and $Cl$ $(3.16)$.Since there is a significant difference in electronegativity,the bond exhibits partial ionic character.Therefore,the $P-Cl$ bond is covalent with some ionic character.