The bond dissociation enthalpy of $H_{2(g)}$ and $N_{2(g)}$ are $436 \ kJ \ mol^{-1}$ and $940 \ kJ \ mol^{-1}$ respectively,and the enthalpy of formation of $NH_{3(g)}$ is $-45 \ kJ \ mol^{-1}$. The enthalpy of atomisation of $NH_{3(g)}$ is ..... $kJ \ mol^{-1}$.

  • A
    $ -1079 $
  • B
    $ -1169 $
  • C
    $ 1079 $
  • D
    $ 1169 $

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If for the reaction $CCl_{4(g)} \rightarrow C_{(g)} + 4Cl_{(g)}$ the following data is given:
$\Delta_{vap} H^{\theta} (CCl_{4(l)}) = 30 \ kJ \ mol^{-1}$
$\Delta_{f} H^{\theta} (CCl_{4(l)}) = -136.0 \ kJ \ mol^{-1}$
$\Delta_{a} H^{\theta} (C_{(s)}) = 714.0 \ kJ \ mol^{-1}$
$\Delta_{a} H^{\theta} (Cl_{2(g)}) = 242.0 \ kJ \ mol^{-1}$
Calculate the mean bond enthalpy of $C-Cl$ in $CCl_{4(g)}$.

If the standard heat of the reaction $Fe_2O_{3(s)} + 3CO_{(g)} = 2Fe_{(s)} + 3CO_{2(g)}$ is $-6.6 \, kcal$,then $\Delta H_f^o$ for $Fe_2O_{3(s)}$ is $...... \, kcal/mol$. [Given: $\Delta H_f^o$ of $CO_{(g)} = -26.4 \, kcal$ and $\Delta H_f^o$ of $CO_{2(g)} = -94 \, kcal$]

Explain the bond enthalpy.

If the enthalpy of formation of $N_2O$ is $82 \, kJ \, mol^{-1}$,calculate the resonance energy of $N_2O$ in $kJ \, mol^{-1}$.
$N \equiv N \, (946 \, kJ \, mol^{-1}); \, N = N \, (418 \, kJ \, mol^{-1})$
$O = O \, (498 \, kJ \, mol^{-1}); \, N = O \, (607 \, kJ \, mol^{-1})$

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$C + \frac{1}{2} O_2 \to CO; \Delta H = -42 \ kJ$
$CO + \frac{1}{2} O_2 \to CO_2; \Delta H = -24 \ kJ$
The heat of formation of $CO_2$ is ..... $kJ$.

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