The bond dissociation energies of $X_2$,$Y_2$ and $XY$ are in the ratio of $1 : 0.5 : 1$. $\Delta H$ for the formation of $XY$ is $-200 \ kJ \ mol^{-1}$. The bond dissociation energy of $X_2$ will be $...... \ kJ \ mol^{-1}$.

  • A
    $200$
  • B
    $100$
  • C
    $800$
  • D
    $400$

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If the enthalpy of neutralization of $HCN$ and $NaOH$ is $-12.13 \, kJ/mol$,then the enthalpy of ionization of $HCN$ will be ...... $kJ/mol$.

Heat of combustion of two isomers $x$ and $y$ are $17 \ kJ/mol$ and $12 \ kJ/mol$ respectively. From this information,it may be concluded that:

Based on the following thermochemical reactions:
$H_2O_{(g)} + C_{(s)} \rightarrow CO_{(g)} + H_{2(g)} ; \Delta H = 131 \ kJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow CO_{2(g)} ; \Delta H = -282 \ kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O_{(g)} ; \Delta H = -242 \ kJ$
$C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)} ; \Delta H = x \ kJ$
The value of $x$ will be:

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Given the following data:
Reaction Energy Change (in $kJ$)
$Li_{(s)} \to Li_{(g)}$ $161$
$Li_{(g)} \to Li^{+}_{(g)}$ $520$
$\frac{1}{2} F_{2(g)} \to F_{(g)}$ $77$
$F_{(g)} + e^- \to F^{-}_{(g)}$ (Electron gain enthalpy)
$Li^{+}_{(g)} + F^{-}_{(g)} \to LiF_{(s)}$ $-1047$
$Li_{(s)} + \frac{1}{2} F_{2(g)} \to LiF_{(s)}$ $-617$

Based on the data provided,the value of electron gain enthalpy of fluorine would be $kJ\ mol^{-1}$.

$C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)} \dots \dots(I) \quad \Delta H = -393 \, kJ \, mol^{-1}$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_{2}O_{(l)} \dots \dots(II) \quad \Delta H = -287.3 \, kJ \, mol^{-1}$
$2CO_{2(g)} + 3H_{2}O_{(l)}$ $\rightarrow C_{2}H_{5}OH_{(l)} + 3O_{2(g)} \dots \dots(III) \quad \Delta H = 1366.8 \, kJ \, mol^{-1}$
Find the standard enthalpy of formation of $C_{2}H_{5}OH_{(l)}$.

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